(R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)- 1,2-cyclohexanediaminomanganese(III) chloride

Categories : Chiral Catalysts, Ligands, Reagents, Kinetic Resolution, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, SALENs, Fluorination Catalysts and Ligands, Synthetic Reagents, Fluorination Reagents

Applications : (R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride can be used as a catalyst for asymmetric epoxidation of unfunctionalized olefins,  asymmetric α-hydroxylation of silyl enol ethers, and synthesis of the taxol side chain, and cis-1-amino-2-indanol (which is used in the preparation of a series of potent HIV-1 protease inhibitory peptides)

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Products Features

• Chemical Name : (R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
• Synonyms : (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N’-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen’s Catalyst
• CAS Number : 138124-32-0
• Molecular Formula : [[[(CH₃)₃C]₂C₆H₂-2-(O-)CH=N]₂C₆H₁₀]MnCl
• Molecular Weight : 635.20
• MDL Number : MFCD02101664

Properties

• Melting Point : 330 – 332 °C
• Appearance : Powder
• Color : Dark Brown

Packaging

• 1 gm, 10 gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Price and Availability