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(Acetylacetonato) dicarbonylrhodium(I)

(Acetylacetonato) dicarbonylrhodium(I)

Categories : Rhodium (Rh) Catalysts, Inorganic Chemistry and Catalysis, Chemical Synthesis, Catalysts, Catalysis, Materials Science, Solution Deposition Precursor.

Applications :

(Acetylacetonato)dicarbonylrhodium(I) can be used as a catalyst for

1) Hydroformylation of olefins [Ref: Synthesis, 2001, 1; Org. Lett., 2009, 11, 2659]

2)  Silylformylation of olefins [Ref: J. Am. Chem. Soc., 1997, 119, 12416]

3) Carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids [Ref: J. Am. Chem. Soc., 2009, 131, 14188]

4) Conjugate addition of aryl- and alkenylboronic acids to enones [Ref:  Organometallics, 1997, 16, 4229; Org. Lett., 2009, 11, 971]



CAS Number
#14874-82-9
Synonyms
Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rh(CO)2acac, Rhodium(I) dicarbonyl acetylacetonate
Molecular Formula
C7H7O4Rh
EC Number
238-947-9
MDL Number
MFCD00009884
Chemical Name
(Acetylacetonato)dicarbonylrhodium(I)
Molecular Weight
258.03
Melting Point
154-156 °C(lit.)
Purity
Above 98%
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color
Red/green

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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(Acetylacetonato) dicarbonylrhodium(I) | Synthesis with Catalysts

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