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Bis(triphenylphosphine)palladium(II) dichloride

Bis(triphenylphosphine)palladium(II) dichloride

Applications:

Bis(triphenylphosphine)palladium(II) dichloride can be used as a catalyst in:

1) Carbonylative cyclization of malonate derivatives (Ref:  J. Am. Chem. Soc., 1989, 111, 8018; Tetrahedron Lett., 1990, 31, 2841)

2) Double allylation of activated olefins (Ref: J. Am. Chem. Soc., 1997, 119, 8113) 

3) Preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans (Ref: J. Org. Chem., 2001, 66, 175)

4) Homocoupling of terminal alkynes (Ref: J. Org. Chem., 2002, 67, 1969)

5) Cross-coupling of alkynylsilanols and aryl halides (Ref: J. Org. Chem., 2003, 68, 9151)

6) Alkynylation of N-fused heterocycles (Ref: J. Am. Chem. Soc., 2007, 129, 7742)

7) Arylation of tautomerizable heterocycles (Ref: Angew. Chem. Int. Ed., 2008, 47, 4711)

8) Tandem Heck reaction/C-H functionalization (Ref: J. Am. Chem. Soc., 2008, 130, 11300)

CAS Number
#13965-03-2
Synonyms
trans-Dichlorobis(triphenylphosphine)palladium(II)
Molecular Formula
C36H30Cl2P2Pd
EC Number
237-744-2
MDL Number
MFCD00009593
Chemical Name
Bis(triphenylphosphine)palladium(II) dichloride
Molecular Weight
701.9
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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Bis(triphenylphosphine)palladium(II) dichloride | Synthesis with Catalysts

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