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Dihydridocarbonyltris(triphenylphosphine)ruthenium

Dihydridocarbonyltris(triphenylphosphine)ruthenium

Categories : Ruthenium (Ru) Catalysts, Inorganic Chemistry and Catalysis, C-H activation, Chemical Synthesis, Catalysts, Catalysis

Applications : 

Dihydridocarbonyltris(triphenylphosphine)ruthenium is used as a catalyst for

1) C-C bond formation reactions [Ref: J. Am. Chem. Soc., 2009, 131, 7238; Org. Lett., 2009, 11, 855; J. Am. Chem. Soc., 2007, 129, 6098]

2) Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation [Ref: Dalton Trans., 2009, 716; Adv. Synth. Catal., 2008, 350, 1975]

3) Rearrangement of oximes to amides

4) Oxidation of primary alcohols to methyl esters

5) Conversion of 1,4-alkynediols into pyrroles 

CAS Number
#25360-32-1
Synonyms
Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II)
Molecular Formula
C55H47OP3Ru
MDL Number
MFCD00015870
Chemical Name
Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
Molecular Weight
919.79
Melting Point
161 - 163 °C
Solubility
Insoluble in water
Purity
98.60%
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color
Light Grey

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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Dihydridocarbonyltris(triphenylphosphine)ruthenium | Synthesis with Catalysts

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