Dihydridocarbonyltris(triphenylphosphine)ruthenium

Categories : Ruthenium (Ru) Catalysts, Inorganic Chemistry and Catalysis, C-H activation, Chemical Synthesis, Catalysts, Catalysis

Applications :

Dihydridocarbonyltris(triphenylphosphine)ruthenium is used as a catalyst for

1) C-C bond formation reactions [Ref: J. Am. Chem. Soc., 2009, 131, 7238; Org. Lett., 2009, 11, 855; J. Am. Chem. Soc., 2007, 129, 6098]

2) Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation [Ref: Dalton Trans., 2009, 716; Adv. Synth. Catal., 2008, 350, 1975]

3) Rearrangement of oximes to amides

4) Oxidation of primary alcohols to methyl esters

5) Conversion of 1,4-alkynediols into pyrroles

CAS Number

#25360-32-1

Synonyms

Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II)

Molecular Formula

C₅₅H₄₇OP₃Ru

MDL Number

MFCD00015870

Chemical Name

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Molecular Weight

919.79

Melting Point

161 - 163 °C

Solubility

Insoluble in water

Purity

98.60%

Packaging

1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Color

Light Grey

Price and Availability

Quantity	Availability	*Price (INR)
1 gm	In Stock	On Request
10 gm	In Stock	On Request
50 gm	In Stock	On Request
1 kg	4-5 Weeks	On Request
25 kg	8-10 Weeks (Negotiable)	On Request

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Dihydridocarbonyltris(triphenylphosphine)ruthenium | Synthesis with Catalysts

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Dihydridocarbonyltris(triphenylphosphine)ruthenium