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(S)-DM-BINAP

(S)-DM-BINAP

Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

Applications:

(S)-DM-BINAP has application in :

1. Copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters (Ref: J. Am. Chem. Soc., 2003, 125, 2507)

2. Enantioselective fluorination of oxindoles (Ref: J. Am. Chem. Soc., 2005, 127, 10164)

3. [2+2+2] cycloaddition of tetraynes and hexaynes (Ref: Tetrahedron, 2008, 64, 821)

4. Asymmetric reduction of ketones via ruthenium-catalyzed transfer hydrogenation (Ref: J. Am. Chem. Soc., 2011, 133, 10696)

5. Asymmetric hydroboration of unsaturated imines (Ref: Org. Lett., 2013, 15, 4810)

Note: Please see applications of (S)--BINAP and (S)-T-BINAP for additional applications in which these ligands may be used

CAS Number
#135139-00-3
Synonyms
(S)-(−)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1′-binaphthyl, (S)-(−)-2,2′-Bis[di(3,5-xylyl)phoshino]-1,1′-binaphthyl, (S)-3,5-Xylyl-BINAP
Molecular Formula
C52H48P2
MDL Number
MFCD01630821
Chemical Name
(S)-DM-BINAP
Molecular Weight
734.9
Melting Point
255°C
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color
White to light yellow

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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(S)-DM-BINAP | Synthesis with Catalysts

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