(S)-DM-BINAP

Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

Applications:

(S)-DM-BINAP has application in :

1. Copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters (Ref: J. Am. Chem. Soc., 2003, 125, 2507)

2. Enantioselective fluorination of oxindoles (Ref: J. Am. Chem. Soc., 2005, 127, 10164)

3. [2+2+2] cycloaddition of tetraynes and hexaynes (Ref: Tetrahedron, 2008, 64, 821)

4. Asymmetric reduction of ketones via ruthenium-catalyzed transfer hydrogenation (Ref: J. Am. Chem. Soc., 2011, 133, 10696)

5. Asymmetric hydroboration of unsaturated imines (Ref: Org. Lett., 2013, 15, 4810)

Note: Please see applications of (S)--BINAP and (S)-T-BINAP for additional applications in which these ligands may be used

CAS Number

#135139-00-3

Synonyms

(S)-(−)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1′-binaphthyl, (S)-(−)-2,2′-Bis[di(3,5-xylyl)phoshino]-1,1′-binaphthyl, (S)-3,5-Xylyl-BINAP

Molecular Formula

C₅₂H₄₈P₂

MDL Number

MFCD01630821

Chemical Name

(S)-DM-BINAP

Molecular Weight

734.9

Melting Point

255°C

Packaging

1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Color

White to light yellow

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