Synthesis with Catalysts Preloader
  • [email protected]
  • DO-01, UPSIDC Industrial Area, Sikandrabad, Bulandshahar, Uttar Pradesh (INDIA)

(S)-T-BINAP

(S)-T-BINAP

Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, BINAPs

(S)-T-BINAP is a versatile chiral organophosphorus ligand and has been used in several catalytic applications such as: 

1. Palladium catalyzed carbon-oxygen bond formation (Ref: J. Am. Chem. Soc., 1997, 119, 11108) 

2. Palladium-catalyzed α-arylation reaction of ketones (Ref: J. Am. Chem. Soc., 2000, 122, 6797)

3. Cu-catalyzed asymmetric conjugate reduction (Ref: J. Am. Chem. Soc., 1998, 120, 837)

4. Cu-catalyzed asymmetric dienolate addition to aldehydes (Ref: J. Am. Chem. Soc., 2003, 125, 11253)

5. Enantioselective conjugate reduction of lactones and lactams (Ref: Org. Lett., 2003, 5(20), 3691)

6. Enantioselective cycloaddition of allenylsilanes with α-Imino esters (Ref: J. Am. Chem. Soc., 2003, 125, 5644)

7. Catalytic Aldol reaction to ketones (Ref: Org. Lett., 2005, 7(22), 4955)

8. Rhodium catalyzed [2+2+2] cycloaddition reaction of alkenes and alkynes (Org. Lett., 2011, 13, 4692)

9. Iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes (Ref: J. Am. Chem. Soc., 2014, 136, 8911)

10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols (Ref: J. Am. Chem. Soc., 2014, 136, 8911)

11. Rhodium-catalyzed cross cyclotrimerization (Angew. Chem., Int. Ed., 2014, 53, 2956)

Note:  Please check notes for S-BINAP for additional applications


CAS Number
#100165-88-6
Synonyms
(S)-(−)-2,2′-p-tolyl-phosphino)-1,1′-binaphthyl, (S)-Tol-BINAP
Molecular Formula
C48H40P2
MDL Number
MFCD01311709
Chemical Name
(S)-T- BINAP
Molecular Weight
678.78
Melting Point
250-255 °C
Purity
Above 99%
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color
White

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

For bulk inquiries and more details please email us on

Email us

Note*: The images does not represent actual product and product may vary.
(S)-T-BINAP | Synthesis with Catalysts

QUICK CONTACT

If you have any questions or would like to book a session please contact us.

Questions on chemistry, product or process development ? We can help!

Any process, any industry. Please call us with your questions and we will help you solve your problems.