(S,S)-Jacobsen’s catalyst

Chiral Catalysts, Ligands, Reagents, Kinetic Resolution, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, SALENs, Fluorination Catalysts and Ligands, Synthetic Reagents, Fluorination Reagents

Applications

(S,S)-Jacobsen’s catalyst is a chiral manganese-salen containing complex that can catalyze a variety of asymmetric transformations such as:

1) Asymmetric epoxidation of olefins (Ref: American Chemical Society 112, 2801-2801, (1990); The Journal of Organic Chemistry 56, 2296-2296, (1991); Journal of the American Chemical Society 113, 7063-7063, (1991); Tetrahedron Letters 32, 5055-5055, (1991))

2) Oxidative kinetic resolution (OKR) of racemic secondary alcohols (Ref: Angew. Chem. Int. Ed. Eng., 2003, 42, 1042)

More About Jacobsen's Catalysts

CAS Number

#135620-04-1

Synonyms

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

Molecular Formula

C₃₆H₅₂ClMnN₂O₂

MDL Number

MFCD02101663

Chemical Name

(S,S)-(+)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)chloride

Molecular Weight

635.2 g /mol

Melting Point

330 - 332 °C

Packaging

1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Color

Dark Brown

Price and Availability

Quantity	Availability	*Price (INR)
1 gm	In Stock	On Request
10 gm	In Stock	On Request
50 gm	In Stock	On Request
1 kg	4-5 Weeks	On Request
25 kg	8-10 Weeks (Negotiable)	On Request

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(S,S)-Jacobsen’s catalyst | Synthesis with Catalysts

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(S,S)-Jacobsen’s catalyst