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(S,S)-Jacobsen’s catalyst

(S,S)-Jacobsen’s catalyst

 Chiral Catalysts, Ligands, Reagents, Kinetic Resolution, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, SALENs, Fluorination Catalysts and Ligands, Synthetic Reagents, Fluorination Reagents

Applications

(S,S)-Jacobsen’s catalyst is a chiral manganese-salen containing complex that can catalyze a variety of asymmetric transformations such as:   

1) Asymmetric epoxidation of olefins (Ref: American Chemical Society 112, 2801-2801, (1990); The Journal of Organic Chemistry 56, 2296-2296, (1991); Journal of the American Chemical Society 113, 7063-7063, (1991); Tetrahedron Letters 32, 5055-5055, (1991))

2) Oxidative kinetic resolution (OKR) of racemic secondary alcohols (Ref: Angew. Chem. Int. Ed. Eng., 2003, 42, 1042)


CAS Number
#135620-04-1
Synonyms
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Molecular Formula
C36H52ClMnN2O2
MDL Number
MFCD02101663
Chemical Name
(S,S)-(+)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)chloride
Molecular Weight
635.2 g /mol
Melting Point
330 - 332 °C
Packaging
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color
Dark Brown

Price and Availability


QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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(S,S)-Jacobsen’s catalyst | Synthesis with Catalysts

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